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Tetrazol-5-ylidene Gold(III) Complexes
Tetrazol-5-ylidene Gold(III) Complexes from Sequential [2 + 3] Cycloaddition of Azide to Metal-Bound Isocyanides and N4 Alkylation Full text: Organometallics, 2017, 36, 3974–3980
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Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides
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Reactivity of acyclic diaminocarbene ligands
Reactivity of acyclic diaminocarbene ligands Coord. Chem. Rev. , 2019 , 399, 213014 Write for free PDF
Cyclometalated Platinum(II) Complexes Simultaneously Catalyze and Function as Luminophores
Cyclometalated Platinum(II) Complexes Simultaneously Catalyze the Cross-Linking of Polysiloxanes and Function as Luminophores Full text: ACS Appl. Polym. Mater., 2021, 3, 857 Write for free PDF A family of the C,N-cyclometalated species [Pt(ppy)Cl(PPh3)], [Pt(ppy)Cl(CNCy)], [Pt(ppy)(CNCy)(PPh3)](OTf), and [Pt(ppy)(CNCy)2](BF4) (ppy = 2-phenylpyridinato-C2,N; Cy = cyclohexyl) was generated from [Pt(ppy)(μ-Cl)]2, CNCy, and PPh3. The obtained platinum(II) complexes were characterized by high-resolution ESI+-MS, IR, and 1D (1H, 13C{1H}, 195Pt{1H}) and 2D (1H,1H-NOESY; 1H,13C-HSQC; 1H,13C-HMBC) NMR spectroscopy, and the latter three complexes were investigated by X-ray diffraction. All four platinum species were examined as hydrosilylation catalysts (c 10–4–10–3 M; 80–120 °C; [Pt(ppy)Cl(PPh3)] exhibited the highest catalytic activity) for the cross-linking of vinyl-terminated polydimethylsiloxane and polymethylhydrosiloxane to achieve luminescent silicone rubbers. Each solid complex and the...
The Doctor of Chemical Sciences degree
Diaminocarbene complexes of late transition metals: precursors, synthesis and properties Audio and video recording (Russian) Audio and video recording (English translation)
The Role of Halogen Bonding in Solubility
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Four-Center Nodes
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