The Doctor of Chemical Sciences degree


 




Diaminocarbene complexes of late transition metals: precursors, synthesis and properties

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Complexes with Acyclic Diaminocarbene Ligands (A Review)

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Tuning the Luminescence of Transition Metal Complexes with Acyclic Diaminocarbene Ligands

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Organometallics featuring acyclic diaminocarbene (ADC) ligands have recently emerged as powerful emitters for use in OLEDs and other electroluminescent technologies. Owing to strong σ-donor properties and broad synthetic availability, ADCs have successfully challenged the application of other ancillary ligands for fine-tuning of luminescence emission. This review systematises the data reported concerning the preparation of the luminescent metal complexes bearing ADC ligands, uncover their photophysical properties as a function of carbene ligand structure and metal characteristics as well as draw attention to the potential that application of metal-ADCs provides to the family of transition-metal-based phosphors. Inorg. Chem. Front., 2022, Accepted Manuscript
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