Tetrazol-5-ylidene Gold(III) Complexes
Tetrazol-5-ylidene Gold(III) Complexes from Sequential [2 + 3] Cycloaddition of Azide to Metal-Bound Isocyanides and N4 Alkylation Full text: Organometallics, 2017, 36, 3974–3980
Popular posts from this blog
Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides
Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Structure of the Nucleophile Full text: Organometallics , 2016 , 35, 2, 218 – 228
Reactivity of acyclic diaminocarbene ligands
Reactivity of acyclic diaminocarbene ligands Coord. Chem. Rev. , 2019 , 399, 213014 Write for free PDF
Cyclometalated Platinum(II) Complexes Simultaneously Catalyze and Function as Luminophores
Cyclometalated Platinum(II) Complexes Simultaneously Catalyze the Cross-Linking of Polysiloxanes and Function as Luminophores Full text: ACS Appl. Polym. Mater., 2021, 3, 857 Write for free PDF A family of the C,N-cyclometalated species [Pt(ppy)Cl(PPh3)], [Pt(ppy)Cl(CNCy)], [Pt(ppy)(CNCy)(PPh3)](OTf), and [Pt(ppy)(CNCy)2](BF4) (ppy = 2-phenylpyridinato-C2,N; Cy = cyclohexyl) was generated from [Pt(ppy)(μ-Cl)]2, CNCy, and PPh3. The obtained platinum(II) complexes were characterized by high-resolution ESI+-MS, IR, and 1D (1H, 13C{1H}, 195Pt{1H}) and 2D (1H,1H-NOESY; 1H,13C-HSQC; 1H,13C-HMBC) NMR spectroscopy, and the latter three complexes were investigated by X-ray diffraction. All four platinum species were examined as hydrosilylation catalysts (c 10–4–10–3 M; 80–120 °C; [Pt(ppy)Cl(PPh3)] exhibited the highest catalytic activity) for the cross-linking of vinyl-terminated polydimethylsiloxane and polymethylhydrosiloxane to achieve luminescent silicone rubbers. Each solid complex and the...
The Doctor of Chemical Sciences degree
Diaminocarbene complexes of late transition metals: precursors, synthesis and properties Audio and video recording (Russian) Audio and video recording (English translation)
The Role of Halogen Bonding in Solubility
The Role of Solvent···Complex Halogen Bonding in Solubility of Organometallic Species Full text: Angew. Chem. Int. Ed., 2018, 57, 12785 Write for free PDF
Four-Center Nodes
Four-Center Nodes: Supramolecular Synthons Based on Cyclic Halogen Bonding Chem. Eur. J., 2019, 25, 13671